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You return home to find that your baby brother has scattered his toy trains and trucks all over the floor of your room.As you begin to pick up the toys and put them away,you realize that even though he is just a baby,he has clearly mastered


A) the first law of thermodynamics.
B) the second law of thermodynamics.
C) potential energy.
D) free energy.

E) A) and B)
F) B) and C)

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When the substrate is bound to the enzyme,the shape of the enzyme may change slightly,leading to


A) a better induced fit.
B) a great range of possible catalytic activities.
C) a greater supply of activation energy.
D) more permanent binding through intimate total contact.
E) more possible products of the reaction.

F) All of the above
G) A) and D)

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A molecule that closely resembles the shape of a substrate for an enzyme might serve as a(n)


A) an enzyme
B) allosteric modulator
C) competitive inhibitor
D) pathway blocker

E) B) and D)
F) C) and D)

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Free energy is the amount of energy available for the cell to carry out its many chemical processes.It is the difference between the internal energy or enthalpy and ______ or disorder.


A) free energy
B) entropy
C) chaos
D) heat

E) B) and C)
F) B) and D)

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B

Which of the following statements concerning redox reactions are false?


A) The reduced form of a molecule has a higher level of energy than the oxidized form.
B) Reduction is the gain of an electron,and oxidation is the loss of an electron.
C) Organisms can derive energy from the oxidation of organic compounds.
D) Oxidation reactions and reduction reactions occur independently.

E) B) and C)
F) A) and D)

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Each of the significant properties of a cell (its growth,reproduction,and responsiveness to its environment) requires ________.


A) energy
B) light
C) mitosis
D) movement

E) B) and C)
F) None of the above

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Allosteric inhibitor binds here;changes enzyme shape.


A) active site
B) substrate
C) coenzyme
D) non-catalytic binding site

E) All of the above
F) C) and D)

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Shivering is the result of uncontrollable contractions of skeletal muscle tissue in an effort to increase heat production and raise body temperature.How does this process relate to ATP hydrolysis?


A) ATP is converted directly to heat.
B) Muscle contractions in the form of shivering produces heat and warms the body.
C) ATP hydrolysis causes muscle contraction.
D) Muscle contractions require ATP hydrolysis.Energy is liberated by ATP hydrolysis and converted into heat.

E) B) and C)
F) A) and C)

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In a chemical reaction in a living system,enzymes are used as catalysts.Which of the following statements about enzymes is incorrect?


A) Enzymes enter reactions and can be reused.
B) Enzymes speed up chemical reactions in living systems.
C) Enzymes reduce the energy of activation necessary for a chemical reaction to go forward.
D) Enzymes increase the energy of activation necessary for a chemical reaction to go forwarD.
E) Enzymes are sometimes referred to as biological catalysts;however,not all biological catalysts are proteins.

F) A) and E)
G) A) and D)

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The chief energy currency of all cells is a molecule called


A) cyclic AMP.
B) NADH.
C) FADH.
D) ATP.
E) ADP.

F) A) and E)
G) A) and D)

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Life's ultimate source of energy is derived from


A) the sun.
B) plants.
C) water.
D) air.
E) cells.

F) A) and D)
G) A) and E)

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ATP gives up energy when it is converted to


A) DNA.
B) NADP.
C) NADH.
D) ADP and phosphate.
E) RNA.

F) B) and E)
G) C) and E)

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If you were able to increase the kinetic energy of the molecules inside your body,your body temperature would


A) increase.
B) decrease.
C) remain the same.

D) A) and B)
E) None of the above

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At the conclusion of an enzyme catalyzed reaction,the enzyme


A) must be resynthesized from its amino acids.
B) frees itself from the product and is ready to be reused.
C) must be transported from outside of the cell.
D) changes into an active form.
E) closes up its active site and cannot bind to more substratE.

F) A) and D)
G) A) and E)

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Enzymes are very specific in their choices of substrates because each different enzyme has an active site that


A) depends on unusual amino acids not common in proteins.
B) has a certain unique amino acid to fit each substrate.
C) is shaped to fit a certain substrate molecule.
D) is lined with glycolipids and glycoproteins.
E) passes electrons from one part of the substrate to another.

F) D) and E)
G) A) and C)

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C

If the Ξ”\Delta G of a reaction was -31.45 kJoules,you would know that


A) the reaction would proceed spontaneously.
B) the reaction requires an energy input of 31.45 kJoules to proceed.
C) the products of the reaction have more free energy than the reactants.
D) it is an energonic reaction.

E) A) and D)
F) B) and C)

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Enzymes work most effectively at


A) their optimum pH and temperature conditions
B) all pH and temperature conditions
C) only one temperature and a specific pH

D) B) and C)
E) None of the above

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Protein catalysts that speed up the various metabolic biological reactions in an organism are called


A) substrates.
B) cofactors.
C) reactants.
D) products.
E) enzymes.

F) All of the above
G) A) and E)

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E

Certain key molecules can regulate biochemical pathways by controlling the rates of enzymatic reactions by binding at _________ sites.


A) catalytic
B) enzymatic
C) active
D) allosteric

E) A) and B)
F) A) and C)

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The term oxidation is derived from the name of the element oxygen.This is reasonable,because oxygen


A) attracts electrons very strongly.
B) can be oxidized by accepting electrons.
C) contains more electrons than are needed.
D) can react chemically readily in its gas state.
E) is present everywherE.

F) B) and E)
G) C) and D)

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